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dc.creatorLi, Yuzhan
dc.creatorKessler, Michael
dc.date.accessioned2015-11-05T05:13:52Z
dc.date.available2015-11-05T05:13:52Z
dc.date.issued2013
dc.identifier.urihttp://hdl.handle.net/2376/5555
dc.description.abstractA biphenyl based epoxy monomer, 4,4′-diglycidyloxybiphenyl (BP), was synthesized and cured with a tetra-functional amine, sulfanilamide (SAA), to obtain a liquid crystalline epoxy network. The curing behavior of BP with SAA was studied using differential scanning calorimetry, polarized optical microscopy, and parallel plate rheology. Macroscopic orientation of the liquid crystalline epoxy resins (LCERs) was achieved by curing in a high strength magnetic field, and quantified by an orientation parameter determined with wide angle X-ray diffraction. The effects of orientation on the glass transition temperature, coefficient of thermal expansion, and dynamic mechanical properties of the LCERs were investigated. The results reveal that the formation of the liquid crystalline phase has a dramatic influence on the curing reaction, leading to a decrease in viscosity of the reacting system. Oriented LCERs exhibit anisotropic thermal expansion behavior and significant improvements of thermomechanical properties.en_US
dc.languageEnglish
dc.publisherPolymer
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectLiquid crystalline epoxy resins (LCERs), Magnetic field orientation, Thermomechanical properties
dc.titleLiquid crystalline epoxy resin based on biphenyl mesogen: Effect of magnetic field orientation during cure
dc.typeArticle
dc.description.citationY. Li, M. R. Kessler: Liquid Crystalline Epoxy Resin Based on Bisphenol Mesogen: Effect of Magnetic Field Orientation During Cure, Polymer, 2013, 54 (21), 5742-5746. doi:10.1016/j.polymer.2013.08.005.


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  • Kessler, Michael
    This collection features research by Michael Kessler, professor in the School of Mechanical and Materials Engineering at Washington State University.

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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
Except where otherwise noted, this item's license is described as Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International