Show simple item record

dc.creatorChen, Ruqi
dc.creatorZhang, Chaoqun
dc.creatorKessler, Michael
dc.date.accessioned2015-11-06T21:21:53Z
dc.date.available2015-11-06T21:21:53Z
dc.date.issued2015
dc.identifier.urihttp://hdl.handle.net/2376/5584
dc.descriptionThis article is under embargo until January 2016 per publisher policy.en_US
dc.description.abstractBio-based polyols from epoxidized soybean oil and different fatty acids were successfully prepared using a solvent-free method in order to investigate the effect of the polyols' OH numbers on the thermal and mechanical properties of the polyurethanes prepared using them. Epoxidized soybean oil/epoxidized linseed oil was ring-opened by methanol/glycol followed by saponification to prepare polyhydroxy fatty acids. These fatty acids and epoxidized soybean oil were then used for further solvent-free ring-opening reactions with DBU as catalyst, which facilitated the carboxylic ring-opening. Gel permeation chromatography revealed that a molar ratio of carboxylic acid from polyhydroxy fatty aicds and epoxy group of 0.5 : 1 resulted in optimized polyols containing the smallest amounts of residual starting materials. The obtained polyols had varying OH numbers and the acquired polyurethane films were comprehensively characterized. With increasing OH number of the polyols the PUs displayed an increase in crosslinking density, glass transition temperature (Tg), tensile strength and Young's modulus, and a decrease in elongation and toughness. This work provides Supporting Information on the effect of OH number of polyols obtained via a solvent-free ring-opening method on the mechanical and thermal properties of polyurethanes, of particular interest when designing PU products for specific purposes.en_US
dc.languageEnglish
dc.publisherJournal of Applied Polymer Science
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectbiopolymers and renewable polymers
dc.subjectfilms
dc.subjectglass transition
dc.subjectpolyurethanes
dc.subjectthermosets
dc.titlePolyols and polyurethanes prepared from epoxidized soybean oil ring-opened by polyhydroxy fatty acids with varying OH numbers
dc.typeArticle
dc.description.citationR. Chen, C. Zhang, M. R. Kessler: Polyols and Polyurethanes Prepared from Epoxidized Soybean Oil Ring-opened by Polyhydroxy Fatty Acids with Varying OH Number, Journal of Applied Polymer Science, 2015, 132(1), 41213. DOI: 10.1002/app.41213.


Files in this item

Thumbnail

This item appears in the following Collection(s)

  • Kessler, Michael
    This collection features research by Michael Kessler, professor in the School of Mechanical and Materials Engineering at Washington State University.

Show simple item record

Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
Except where otherwise noted, this item's license is described as Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International